ThermoPlastic Elastomer
Thermoplastic elastomers (TPE) are a unique combination of properties of both plastics and rubber. These materials have both the flexibility and elasticity of rubber and the thermal processability of plastics. This unique combination has made TPEs one of the most popular materials in various industries.
TPE are typically composed of two or more polymers linked together in a block or branched structure. This structure allows them to have both elastomeric and thermoplastic properties.
Applications of TPEs
TPEs are used in a variety of industries due to their unique properties, including:
Automotive industry: Interior parts of cars such as gear levers, seat covers, and under-hood parts.
Medical industry: Medical gloves, medical tubing, and other medical equipment.
Sports industry: Athletic shoes, balls, and other sports equipment.
Packaging: Flexible packaging, airbags, and protective packaging.
Home use: Home appliances, toys, and other consumer products.
Electronic industry: Protective coverings for cables and electronic components.
ThermoPlastic Elastomer
Products | Grade | Elongation at break | Density (g/mm3) | Tensile strength | Applications | Data Sheet | MSDS |
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ThermoPlastic Elastomer | 200 – 375% | 1.15 – 1.25 g/cm³ | 10 – 45 MPa | ||||
ThermoPlastic Elastomer |
Applications | , , , |
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Related products
Acrylonitrile Styrene Acrylate (ASA)
Acrylonitrile Styrene Acrylate structureASA is typically formed by grafting acrylonitrile and styrene onto an acrylic ester elastomer backbone. The acrylic ester phase provides the material with flexibility and impact resistance, while the acrylonitrile and styrene phases contribute to rigidity, chemical resistance, and surface finish.
Acrylonitrile Styrene Acrylate propertiesAcrylonitrile-Styrene-Acrylate (ASA) polymer exhibits a combination of properties that make it well-suited for outdoor and demanding applications. Acrylonitrile Styrene Acrylate (ASA) polymer is a thermoplastic known for its excellent weather resistance, high impact strength, and UV stability, making it ideal for outdoor applications. It combines the toughness of acrylonitrile, the rigidity of styrene, and the weather-resistant properties of acrylic ester, resulting in a material that maintains its color, gloss, and mechanical integrity even under prolonged exposure to sunlight and harsh environmental conditions. ASA is resistant to chemicals, heat, and environmental stress cracking, and it exhibits good processability, enabling it to be molded into complex shapes. Its durability and aesthetic qualities make it suitable for use in automotive parts, outdoor furniture, and building materials.
ApplicationAutomotive Industry
- Exterior Components: Used for manufacturing exterior parts like side view mirrors, radiator grilles, and trims due to its resistance to UV radiation and harsh weather conditions.
- Interior Components: Employed in dashboards, panels, and other interior parts requiring durability and aesthetic appeal.
- Roofing and Cladding: ASA is used in roofing sheets, siding, and cladding materials for its resistance to fading and cracking when exposed to sunlight.
- Windows and Doors: Frames and profiles made of ASA are durable and maintain their color over time.
- Casing and Enclosures: ASA is used in the production of enclosures for electronic devices, electrical components, and appliances due to its impact resistance and aesthetic surface finish.
- Connectors and Insulators: The polymer is valued for its insulating properties and stability.
- Outdoor Furniture: Widely used for chairs, tables, and other outdoor furniture because it retains color and strength under prolonged exposure to sunlight and rain.
- Household Items: Utilized in kitchen appliances, vacuum cleaners, and other durable goods.
- Filament Material: ASA is a popular material for 3D printing, especially for outdoor applications, as it offers better UV resistance compared to ABS.
Advantages
- High impact strength
- Good Processability
- Weather Resistance
- Color and Gloss Retention
- Durability
Disadvantages
- Limited High-Temperature Resistance
- Flammability
- Lower Strength Compared to Metals
- Environmental Impact
Blow Molding (BLOW)
Types of blow moldingContinuous Extrusion Blow Molding (EBM) Process:
- Molten plastic is continuously extruded in a tube-like form (parison).
- A mold clamps around the parison and inflates it with air.
- The part cools and solidifies before being ejected.
- Reciprocating Screw System: The screw moves back and forth to accumulate plastic before pushing it into the mold.
- Accumulator Head System: Plastic is stored in an accumulator before being discharged in a single shot.
- Plastic is first injection molded into a preform (small tube-like shape with a finished neck).
- The preform is then transferred to a blow mold and inflated.
- The final shape is formed, cooled, and ejected.
- Similar to IBM, but includes a stretching step before inflation to improve strength and clarity.
- The preform is reheated, stretched lengthwise, and then blown into shape.
- A parison is extruded and clamped in a mold.
- The parison is stretched both axially (lengthwise) and radially (outward) before being inflated.
Advantages of blow molding
- Cost-Effective Production
- High Efficiency & Fast Production
- Ability to Produce Complex Shapes
- Lightweight and Durable Products
- Versatile Material Usage
- Suitable for Large & Small Products
Disadvantages of blow molding
- Limited to Hollow Shapes
- High Initial Equipment & Mold Costs
- Inconsistent Wall Thickness
- Weak Seams & Stress Points
- Less Precision Compared to Injection Molding
- High Energy Consumption
Applications of blow molding
- packaging Industry: Bottles for beverages, cosmetics, pharmaceuticals, and household products.
- Automotive Industry: Fuel tanks, air ducts, washer fluid reservoirs, and coolant tanks.
- Industrial & Chemical Storage: Drums, barrels, IBCs, and spray bottles.
- Medical & Pharmaceutical: IV bottles, medicine containers, and diagnostic device housings.
- Consumer Goods: Toys, furniture components, water bottles, and detergent containers.
- Construction Industry: Water tanks, septic tanks, pipes, and conduits.
- Agriculture Industry: Pesticide and fertilizer containers, watering cans, and irrigation components.
Emulsion
StructurePVC emulsion grade is a fine-particle polymer produced through emulsion polymerization, resulting in a high molecular weight material with excellent dispersion and film-forming properties. Its structure consists of small, porous particles that readily absorb plasticizers, making it ideal for flexible and soft applications. The polymer chains in emulsion-grade PVC are densely packed, contributing to its superior adhesion, smooth surface finish, and enhanced mechanical properties. Unlike suspension-grade PVC, which has larger and more irregular particles, emulsion-grade PVC exhibits a uniform texture and lower gelation temperature, making it suitable for applications such as synthetic leather, vinyl flooring, medical gloves, and textile coatings. This structural composition allows for easy processing in plastisols and organosols, ensuring a high degree of flexibility, durability, and aesthetic appeal in the final products.
PropertiesPVC emulsion grade is a fine-particle, high molecular weight polymer known for its excellent dispersion and film-forming properties. It has a small particle size, typically in the range of 0.1–2.0 microns, which allows for superior surface finish and enhanced mechanical strength in end applications. This grade of PVC exhibits good plasticizer absorption, making it ideal for flexible and soft products such as synthetic leather, flooring, coatings, and dip-molded goods. It also offers high viscosity in plastisol form, ensuring uniform application in coatings and pastes. Additionally, PVC emulsion grade demonstrates good chemical resistance, durability, and thermal stability, making it suitable for a wide range of industrial and consumer applications.
Applications of PVC Emulsion Grade:
- Synthetic Leather – Used in the production of artificial leather for furniture, automotive upholstery, and fashion accessories.
- Coatings & Paints – Provides a smooth and durable finish in coatings for fabrics, wallpapers, and flooring.
- Dipping Products – Used in medical gloves, toys, and tool grips due to its excellent film-forming properties.
- Flooring & Wall Coverings – Applied in vinyl flooring, wall coverings, and laminates for enhanced durability and aesthetics.
- Printing Inks – Improves adhesion and flexibility in specialized printing inks.
- Automotive & Construction – Utilized in automotive interiors and flexible membranes in construction applications.
Advantages of PVC Emulsion Grade:✔ Excellent Film Formation – Ensures smooth, uniform coatings and films. ✔ High Plasticizer Absorption – Enables flexibility and softness in final products. ✔ Good Chemical & Weather Resistance – Resistant to moisture, chemicals, and UV exposure, enhancing durability. ✔ Fine Particle Size – Allows superior surface finish and controlled viscosity in plastisol applications. ✔ Versatility – Suitable for a wide range of industrial and consumer applications.
Disadvantages of PVC Emulsion Grade:✖ Environmental Concerns – Contains plasticizers and additives that may cause pollution or health risks if not properly managed. ✖ Processing Sensitivity – Requires precise temperature control during processing to prevent degradation. ✖ Lower Heat Resistance – Can soften or degrade at high temperatures, limiting its use in extreme conditions. ✖ Limited Biodegradability – Like other PVC types, it does not decompose easily, posing disposal challenges.
Ethylene TetraFluoroEthylene (ETFE)
StructureEthylene Tetrafluoroethylene (ETFE) is a copolymer composed of ethylene (C₂H₄) and tetrafluoroethylene (C₂F₄) units. Its molecular structure consists of a repeating chain of carbon atoms bonded to both fluorine and hydrogen atoms, giving it a unique combination of chemical resistance, mechanical strength, and thermal stability. The presence of fluorine atoms enhances its non-stick properties and high resistance to UV radiation, while the ethylene component contributes to its flexibility and toughness. Unlike polytetrafluoroethylene (PTFE), ETFE has a lower fluorine content, making it slightly less chemically inert but significantly stronger and more impact-resistant. This structural composition results in a lightweight, durable material that retains its transparency and mechanical properties even under extreme environmental conditions. ETFE's semi-crystalline structure also allows it to be processed into thin films, making it highly suitable for architectural applications, insulation, and protective coatings.
PropertiesEthylene Tetrafluoroethylene (ETFE) possesses a unique combination of properties that make it highly versatile across various applications. It is exceptionally lightweight, weighing only about 1% of the weight of glass, while maintaining high tensile strength and impact resistance. Its chemical structure provides outstanding resistance to ultraviolet (UV) radiation, weathering, and most chemicals, ensuring long-term durability in harsh environments. ETFE is highly transparent, allowing up to 95% of natural light to pass through, making it an excellent choice for architectural applications. Additionally, it has a low coefficient of friction, giving it self-cleaning and anti-fouling properties. The material is also highly flexible, capable of stretching up to three times its original length without losing integrity. With a high melting point of around 265°C (509°F), ETFE exhibits excellent thermal stability and can withstand extreme temperature fluctuations without degradation. Furthermore, it is a recyclable material, adding to its sustainability by reducing environmental impact. These combined properties make ETFE a preferred choice for applications in construction, aerospace, medical, and renewable energy industries.
Advantages
- Lightweight: Weighs only about 1% of the weight of glass.
- High Strength & Durability: Resistant to mechanical stress, impact, and punctures.
- Transparency: Allows up to 95% natural light transmission.
- UV & Weather Resistance: Does not degrade under prolonged sunlight exposure.
- Chemical Resistance: Withstands most acids, solvents, and other harsh chemicals.
- Self-Cleaning Surface: Low friction and non-stick properties prevent dirt accumulation.
- Thermal Stability: Can withstand extreme temperatures (-185°C to 150°C).
- Flexibility & Elasticity: Can stretch up to three times its length without damage.
- Eco-Friendly & Recyclable: Can be melted down and reused.
Disadvantages
- Higher Cost: More expensive than traditional materials like glass or polycarbonate.
- Flammability Concerns: Can burn under extreme conditions but is self-extinguishing.
- Limited Structural Support: Needs additional framing or inflation systems for strength.
- Softness & Scratch Sensitivity: Can be scratched more easily than glass.
- Noise Insulation: Provides less soundproofing compared to solid materials.
Applications
- Architecture & Construction: Used in stadiums, skylights, and domes (e.g., Allianz Arena, Eden Project).
- Aerospace & Automotive: Used for wire insulation and protective coatings.
- Medical Industry: Used for tubing, catheters, and biocompatible coatings.
- Chemical Industry: Lining for pipes and tanks due to its chemical resistance.
- Solar & Renewable Energy: Used in photovoltaic panel coatings and greenhouse covers.
- Electronics: Used in high-performance cable insulation for aerospace and telecommunications.
High Impact PolyStyrene (HIPS)
High Impact PolyStyrene StructureStructure: HIPS consists of long chains of polystyrene in which fine particles of a rubber polymer are distributed. These particles act as a kind of “shock absorber” and prevent cracks from propagating in the polymer.
High Impact PolyStyrene propertieshigh impact polystyrene hips has a combination of properties that make it a versatile and widely used material. It is rigid, impact-resistant, lightweight, easy to process, and has a low melting point. HIPS is also resistant to chemicals, oils, and grease. HIPS has a tensile strength of 24.8 MPa (3,600 psi) and tensile modulus of 1.8 GPa (261 ksi) according to ASTM standards, this plastic is capable of withstanding enough force to make it a suitable choice for the packaging industry, and many other products as well.
ApplicationsFrom the grocery store to the packaging plant to the factory floor, this versatile plastic is a staple across all sorts of sectors. Some examples are:
- Knives, forks, and spoons in the food grade industry use HIPS Plastic.
- Elongated profiles found on display stands are created from HIPS Plastic.
- Containers and trays in the packaging industry
- HIPS plastic makes lightweight tubing and profiles common to household goods
- high impact polystyrene uses creates molded parts used to assemble toys
High Impact PolyStyrene advantages
- more environmentally friendly than other plastics
- High Impact Resistance
- Highly Malleable
- Ability to Paint
- Affordable Price
High Impact PolyStyrene disadvantages
- HIPS is vulnerable to degradation by many chemicals, including solvents, acids, and alkalis.
- HIPS has a low-temperature resistance and can become brittle at low temperatures.
- HIPS has limited resistance to UV light and can become yellow and brittle over time when exposed to UV light.
- HIPS has poor flame resistance and will ignite and burn easily.
Linear Low Density Polyethylene (LLDPE)
StructureLLDPE has a unique linear molecular structure with short, controlled branches. This structure is different from LDPE (Low-Density Polyethylene), which has long and irregular branches. LLDPE consists of ethylene monomers (–CH₂–CH₂–) linked in a linear fashion. It has short, uniform side branches created by copolymerizing ethylene with α-olefins (like butene, hexene, or octene).These branches prevent the polymer chains from packing too tightly, giving LLDPE low density and flexibility.
PropertiesLLDPE (Linear Low-Density Polyethylene) is a versatile thermoplastic polymer known for its excellent flexibility, high impact resistance, and good tensile strength. it is slightly denser than LDPE but less rigid than HDPE, making it ideal for applications requiring toughness and stretchability. It has a high elongation at break (>500%), allowing it to withstand significant stretching without tearing. LLDPE exhibits excellent chemical resistance against acids, bases, and alcohols while maintaining low water absorption, making it suitable for moisture-sensitive applications. Thermally, it has a melting point of approximately 110–125°C and remains functional between -50°C and 60°C. Though it lacks inherent UV resistance, stabilizers can be added to improve durability under sunlight. Its ease of processing through extrusion, blow molding, and film manufacturing makes it widely used in plastic films, flexible tubing, cable insulation, and various molded products. While lldpe is non-biodegradable, it is recyclable, contributing to sustainable material management.
Applications of Linear Low-Density Polyethylene (LLDPE)
- Packaging Industry:
- Stretch films and shrink wraps
- Plastic bags (grocery, trash, and industrial)
- Food packaging films (cling wraps, pouches)
- Agricultural Sector:
- Greenhouse films and mulch films
- Drip irrigation tubing and water storage tanks
- Industrial Applications:
- Pipes and fittings (flexible and durable)
- Cable insulation and protective coatings
- Industrial liners (chemical and water-resistant)
- Automotive Industry:
- Fuel tanks and hoses
- Interior soft components and protective covers
- Consumer & Household Products:
- Toys, containers, and household items
- Soft-touch grips and molded parts
- Medical & Pharmaceutical:
- Medical tubing and IV bags
- Sterile packaging films
Advantages of LLDPE
- Higher Flexibility and Toughness:
- More impact-resistant than LDPE
- Maintains durability even at low temperatures
- Excellent Chemical and Moisture Resistance:
- Resistant to acids, bases, and solvents
- Waterproof and corrosion-resistant
- Good Processability
- Lightweight and Cost-Effective
- Better Puncture and Tear Resistance:
- Ideal for thin film applications like stretch wraps
Disadvantages of LLDPE
- Lower Heat Resistance:
- Softens and deforms at high temperatures
- Not suitable for high-temperature applications
- Poor UV Stability:
- Requires UV stabilizers for outdoor use, or it degrades over time
- Lower Stiffness Compared to HDPE:
- Less rigid, making it unsuitable for structural applications
- Limited Gas Barrier Properties:
- Not ideal for gas-tight packaging applications
- Difficult to Process in Some Applications:
- Requires higher processing temperatures compared to LDPE
PolyArylEtherKetone (PAEK)
StructureThe structure of PolyArylEtherKetone (PAEK) consists of a repeating backbone of aromatic rings (aryl groups) connected by ether (-O-) and ketone (-CO-) linkages. These alternating ether and ketone groups provide a unique combination of flexibility and rigidity, contributing to the polymer's high thermal stability, chemical resistance, and mechanical strength. The presence of aromatic rings enhances structural integrity, making the polymer highly resistant to degradation under extreme conditions. The ether linkages add flexibility to the molecular chain, improving processability, while the ketone groups increase the polymer’s resistance to heat and oxidation. The semi-crystalline nature of PAEK arises from the ability of the polymer chains to pack efficiently in an ordered manner, leading to excellent wear resistance and high mechanical performance. Different types of PAEK, such as PEEK, PEK, and PEKK, vary in the arrangement and proportion of these functional groups, influencing their thermal and mechanical properties. This unique molecular structure makes PAEK an ideal choice for high-performance applications in aerospace, medical, automotive, and industrial sectors.
PropertiesPolyArylEtherKetone (PAEK) is a high-performance, semi-crystalline thermoplastic known for its exceptional mechanical, thermal, and chemical properties. It exhibits excellent strength, stiffness, and wear resistance, making it ideal for demanding applications in aerospace, automotive, medical, and oil and gas industries. PAEK has outstanding thermal stability, withstanding continuous use temperatures of up to 250°C, while also demonstrating remarkable resistance to chemicals, including acids, bases, and organic solvents. It possesses low moisture absorption, ensuring dimensional stability even in humid environments. Furthermore, PAEK offers excellent fatigue resistance, making it suitable for long-term load-bearing applications. Its inherent flame retardancy and low smoke emission enhance safety in high-temperature environments. Additionally, PAEK maintains excellent electrical insulation properties, making it valuable for electronic and electrical applications. These unique characteristics make PAEK an advanced material choice for extreme engineering conditions.
Applications of PolyArylEtherKetone (PAEK):
- Aerospace & Automotive: Used in structural components, bearings, and bushings due to its lightweight, high strength, and temperature resistance.
- Medical Devices: Ideal for implants, surgical instruments, and dental components due to biocompatibility and sterilization resistance.
- Oil & Gas Industry: Used in seals, valves, and insulators for its excellent chemical and high-temperature resistance.
- Electronics & Electrical: Utilized in connectors, insulators, and semiconductor manufacturing for its electrical insulation and heat resistance.
- Industrial & Manufacturing: Used in gears, pumps, and wear-resistant parts due to its high mechanical strength and low friction.
Advantages of PolyArylEtherKetone (PAEK):
- High Thermal Stability: Can withstand continuous temperatures up to 250°C.
- Excellent Mechanical Properties: High strength, stiffness, and impact resistance.
- Chemical Resistance: Withstands harsh chemicals, acids, and solvents.
- Low Moisture Absorption: Ensures dimensional stability in humid environments.
- Good Wear & Fatigue Resistance: Ideal for long-term, high-load applications.
- Flame Retardant & Low Smoke Emission: Enhances safety in high-temperature applications.
- Biocompatibility: Suitable for medical implants and surgical devices.
Disadvantages of PolyArylEtherKetone (PAEK):
- High Cost: More expensive than conventional plastics and some high-performance polymers.
- Difficult Processing: Requires high temperatures and specialized equipment for manufacturing.
- Limited Availability: Not as widely produced as other engineering plastics, leading to supply constraints.
- Brittleness at Low Temperatures: Can become less impact-resistant in extreme cold conditions.
PolyPropylene (PP Chemical)
Structure of Polypropylene (PP)Polypropylene (PP) is a semi-crystalline thermoplastic polymer derived from propene (C₃H₆) monomers through the polymerization process.
- Molecular Structure:
- Composed of repeating propylene units (C₃H₆) linked together in a chain-like structure.
- Exists in three main forms:
- Isotactic PP – Most commonly used, with all methyl groups (CH₃) aligned on one side of the polymer chain, resulting in high crystallinity and strength.
- Syndiotactic PP – Alternating arrangement of methyl groups, making it more flexible but less crystalline.
- Atactic PP – Random arrangement of methyl groups, leading to an amorphous structure with low strength.
- Polymerization Process:
- Polypropylene is synthesized using Ziegler-Natta catalysts or metallocene catalysts in industrial polymerization reactions.
- It is classified as a thermoplastic, meaning it can be melted and reshaped multiple times without significant degradation.
Properties of Polypropylene (PP)Polypropylene possesses a combination of mechanical, thermal, and chemical properties, making it ideal for diverse applications.
1. Mechanical Properties:
✔ High Tensile Strength – Strong yet lightweight, making it ideal for packaging and textiles. ✔ Impact Resistance – Can withstand moderate shocks and impacts. ✔ Good Elasticity & Flexibility – Suitable for films, fibers, and flexible containers.2. Thermal Properties:
✔ High Melting Point (~160°C - 170°C) – More heat-resistant than polyethylene (PE). ✔ Low Thermal Conductivity – Acts as an insulating material. ✔ Resistant to Temperature Fluctuations – Can handle both hot and cold environments.3. Chemical Properties:
✔ Resistant to Acids, Alkalis, and Solvents – Does not degrade easily when exposed to chemicals. ✔ Low Water Absorption – Maintains mechanical properties in humid environments. ✔ Good Fatigue Resistance – Ideal for repeated bending applications like hinges.4. Electrical Properties:
✔ Excellent Electrical Insulation – Used in wires, cables, and electrical components.5. Environmental Properties:
✔ Recyclable (#5 plastic code) – Can be reused in eco-friendly applications. ✔ UV Sensitivity – Can degrade when exposed to prolonged UV radiation unless treated with stabilizers.Applications of Polypropylene (PP)
- Packaging Industry
- Textile Industry
- Automotive Industry
- Medical & Healthcare Applications
- Household & Consumer Products
- Industrial Applications
Advantages of Polypropylene (PP)✔ Lightweight & Strong – Provides durability without adding extra weight. ✔ Excellent Chemical Resistance – Withstands exposure to acids, bases, and solvents. ✔ High Heat Resistance – Can be used in microwaves and hot water applications. ✔ Waterproof & Moisture-Resistant – Ideal for food packaging and textiles. ✔ Recyclable & Eco-Friendly – Can be reused, reducing plastic waste. ✔ Affordable & Cost-Effective – Inexpensive compared to other polymers. ✔ Non-Toxic & Safe – Used in medical and food-grade applications.
Disadvantages of Polypropylene (PP)✘ UV Degradation – Can become brittle when exposed to sunlight for long periods unless UV stabilizers are added. ✘ Low Impact Resistance at Low Temperatures – Can crack in extremely cold conditions. ✘ Flammability – Easily combustible and requires flame retardants for certain applications. ✘ Difficult to Paint or Glue – Requires special surface treatments for adhesion. ✘ Limited Transparency – Unlike PET, PP is not completely clear. ✘ Environmental Concerns – Though recyclable, it is not biodegradable, leading to plastic waste issues.
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