ThermoPlastic Elastomer
Thermoplastic elastomers (TPE) are a unique combination of properties of both plastics and rubber. These materials have both the flexibility and elasticity of rubber and the thermal processability of plastics. This unique combination has made TPEs one of the most popular materials in various industries.
TPE are typically composed of two or more polymers linked together in a block or branched structure. This structure allows them to have both elastomeric and thermoplastic properties.
Applications of TPEs
TPEs are used in a variety of industries due to their unique properties, including:
Automotive industry: Interior parts of cars such as gear levers, seat covers, and under-hood parts.
Medical industry: Medical gloves, medical tubing, and other medical equipment.
Sports industry: Athletic shoes, balls, and other sports equipment.
Packaging: Flexible packaging, airbags, and protective packaging.
Home use: Home appliances, toys, and other consumer products.
Electronic industry: Protective coverings for cables and electronic components.
ThermoPlastic Elastomer
Products | Grade | Elongation at break | Density (g/mm3) | Tensile strength | Applications | Data Sheet | MSDS |
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ThermoPlastic Elastomer | 200 – 375% | 1.15 – 1.25 g/cm³ | 10 – 45 MPa | ||||
ThermoPlastic Elastomer |
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Related products
Acrylonitrile Styrene Acrylate (ASA)
Acrylonitrile Styrene Acrylate structureASA is typically formed by grafting acrylonitrile and styrene onto an acrylic ester elastomer backbone. The acrylic ester phase provides the material with flexibility and impact resistance, while the acrylonitrile and styrene phases contribute to rigidity, chemical resistance, and surface finish.
Acrylonitrile Styrene Acrylate propertiesAcrylonitrile-Styrene-Acrylate (ASA) polymer exhibits a combination of properties that make it well-suited for outdoor and demanding applications. Acrylonitrile Styrene Acrylate (ASA) polymer is a thermoplastic known for its excellent weather resistance, high impact strength, and UV stability, making it ideal for outdoor applications. It combines the toughness of acrylonitrile, the rigidity of styrene, and the weather-resistant properties of acrylic ester, resulting in a material that maintains its color, gloss, and mechanical integrity even under prolonged exposure to sunlight and harsh environmental conditions. ASA is resistant to chemicals, heat, and environmental stress cracking, and it exhibits good processability, enabling it to be molded into complex shapes. Its durability and aesthetic qualities make it suitable for use in automotive parts, outdoor furniture, and building materials.
ApplicationAutomotive Industry
- Exterior Components: Used for manufacturing exterior parts like side view mirrors, radiator grilles, and trims due to its resistance to UV radiation and harsh weather conditions.
- Interior Components: Employed in dashboards, panels, and other interior parts requiring durability and aesthetic appeal.
- Roofing and Cladding: ASA is used in roofing sheets, siding, and cladding materials for its resistance to fading and cracking when exposed to sunlight.
- Windows and Doors: Frames and profiles made of ASA are durable and maintain their color over time.
- Casing and Enclosures: ASA is used in the production of enclosures for electronic devices, electrical components, and appliances due to its impact resistance and aesthetic surface finish.
- Connectors and Insulators: The polymer is valued for its insulating properties and stability.
- Outdoor Furniture: Widely used for chairs, tables, and other outdoor furniture because it retains color and strength under prolonged exposure to sunlight and rain.
- Household Items: Utilized in kitchen appliances, vacuum cleaners, and other durable goods.
- Filament Material: ASA is a popular material for 3D printing, especially for outdoor applications, as it offers better UV resistance compared to ABS.
Advantages
- High impact strength
- Good Processability
- Weather Resistance
- Color and Gloss Retention
- Durability
Disadvantages
- Limited High-Temperature Resistance
- Flammability
- Lower Strength Compared to Metals
- Environmental Impact
Blow Molding (BLOW)
Types of blow moldingContinuous Extrusion Blow Molding (EBM) Process:
- Molten plastic is continuously extruded in a tube-like form (parison).
- A mold clamps around the parison and inflates it with air.
- The part cools and solidifies before being ejected.
- Reciprocating Screw System: The screw moves back and forth to accumulate plastic before pushing it into the mold.
- Accumulator Head System: Plastic is stored in an accumulator before being discharged in a single shot.
- Plastic is first injection molded into a preform (small tube-like shape with a finished neck).
- The preform is then transferred to a blow mold and inflated.
- The final shape is formed, cooled, and ejected.
- Similar to IBM, but includes a stretching step before inflation to improve strength and clarity.
- The preform is reheated, stretched lengthwise, and then blown into shape.
- A parison is extruded and clamped in a mold.
- The parison is stretched both axially (lengthwise) and radially (outward) before being inflated.
Advantages of blow molding
- Cost-Effective Production
- High Efficiency & Fast Production
- Ability to Produce Complex Shapes
- Lightweight and Durable Products
- Versatile Material Usage
- Suitable for Large & Small Products
Disadvantages of blow molding
- Limited to Hollow Shapes
- High Initial Equipment & Mold Costs
- Inconsistent Wall Thickness
- Weak Seams & Stress Points
- Less Precision Compared to Injection Molding
- High Energy Consumption
Applications of blow molding
- packaging Industry: Bottles for beverages, cosmetics, pharmaceuticals, and household products.
- Automotive Industry: Fuel tanks, air ducts, washer fluid reservoirs, and coolant tanks.
- Industrial & Chemical Storage: Drums, barrels, IBCs, and spray bottles.
- Medical & Pharmaceutical: IV bottles, medicine containers, and diagnostic device housings.
- Consumer Goods: Toys, furniture components, water bottles, and detergent containers.
- Construction Industry: Water tanks, septic tanks, pipes, and conduits.
- Agriculture Industry: Pesticide and fertilizer containers, watering cans, and irrigation components.
Emulsion
StructurePVC emulsion grade is a fine-particle polymer produced through emulsion polymerization, resulting in a high molecular weight material with excellent dispersion and film-forming properties. Its structure consists of small, porous particles that readily absorb plasticizers, making it ideal for flexible and soft applications. The polymer chains in emulsion-grade PVC are densely packed, contributing to its superior adhesion, smooth surface finish, and enhanced mechanical properties. Unlike suspension-grade PVC, which has larger and more irregular particles, emulsion-grade PVC exhibits a uniform texture and lower gelation temperature, making it suitable for applications such as synthetic leather, vinyl flooring, medical gloves, and textile coatings. This structural composition allows for easy processing in plastisols and organosols, ensuring a high degree of flexibility, durability, and aesthetic appeal in the final products.
PropertiesPVC emulsion grade is a fine-particle, high molecular weight polymer known for its excellent dispersion and film-forming properties. It has a small particle size, typically in the range of 0.1–2.0 microns, which allows for superior surface finish and enhanced mechanical strength in end applications. This grade of PVC exhibits good plasticizer absorption, making it ideal for flexible and soft products such as synthetic leather, flooring, coatings, and dip-molded goods. It also offers high viscosity in plastisol form, ensuring uniform application in coatings and pastes. Additionally, PVC emulsion grade demonstrates good chemical resistance, durability, and thermal stability, making it suitable for a wide range of industrial and consumer applications.
Applications of PVC Emulsion Grade:
- Synthetic Leather – Used in the production of artificial leather for furniture, automotive upholstery, and fashion accessories.
- Coatings & Paints – Provides a smooth and durable finish in coatings for fabrics, wallpapers, and flooring.
- Dipping Products – Used in medical gloves, toys, and tool grips due to its excellent film-forming properties.
- Flooring & Wall Coverings – Applied in vinyl flooring, wall coverings, and laminates for enhanced durability and aesthetics.
- Printing Inks – Improves adhesion and flexibility in specialized printing inks.
- Automotive & Construction – Utilized in automotive interiors and flexible membranes in construction applications.
Advantages of PVC Emulsion Grade:✔ Excellent Film Formation – Ensures smooth, uniform coatings and films. ✔ High Plasticizer Absorption – Enables flexibility and softness in final products. ✔ Good Chemical & Weather Resistance – Resistant to moisture, chemicals, and UV exposure, enhancing durability. ✔ Fine Particle Size – Allows superior surface finish and controlled viscosity in plastisol applications. ✔ Versatility – Suitable for a wide range of industrial and consumer applications.
Disadvantages of PVC Emulsion Grade:✖ Environmental Concerns – Contains plasticizers and additives that may cause pollution or health risks if not properly managed. ✖ Processing Sensitivity – Requires precise temperature control during processing to prevent degradation. ✖ Lower Heat Resistance – Can soften or degrade at high temperatures, limiting its use in extreme conditions. ✖ Limited Biodegradability – Like other PVC types, it does not decompose easily, posing disposal challenges.
Expandable PolyStyrene (EPS)
Expanded PolyStyrene structureThe structure of Expanded Polystyrene (EPS) consists of tiny, closed-cell foam beads made of polystyrene. These beads are expanded using heat, causing them to expand up to 50 times their original size. Also each bead contains air pockets.
Expanded PolyStyrene propertiesExpanded polystyrene (EPS) is found to be the most commonly used polymer core. This is because it is lightweight, resistant to moisture and also it has a long life. Studies have concluded that softening of EPS starts when exposed to temperatures ranging from 100°C to 120°C. In the process of flashovers, EPS melted about 160°C and then vaporized, producing poisonous gases at a temperature of 275°C. EPS is an inert, low density hydrocarbon-derived thermoplastic which contains several spherical beads with 2 percent polystyrene and 98 percent air
Expanded PolyStyrene applicationsBuilding and Construction-EPS is widely used in the building and construction industry due to its insulation properties. It can be used:
- As insulated panel systems for facades, walls, roofs and floors in buildings.
- As flotation material in the construction of marinas and pontoons.
- As a lightweight fill in road and railway construction.
- in the packaging of foodstuffs such as seafood, fruit, and vegetables.
- to produce food service containers like drink cups, food trays, and clamshell containers.
expanded polystyrene advantages
- lightweight
- water-resistant
- easily manufactured
- Energy Efficient
- high Durability and Longevity
expanded polystyrene disadvantages
- vulnerability to compression
- limited fire resistance
- non-biodegradable
PolyArylEtherKetone (PAEK)
StructureThe structure of PolyArylEtherKetone (PAEK) consists of a repeating backbone of aromatic rings (aryl groups) connected by ether (-O-) and ketone (-CO-) linkages. These alternating ether and ketone groups provide a unique combination of flexibility and rigidity, contributing to the polymer's high thermal stability, chemical resistance, and mechanical strength. The presence of aromatic rings enhances structural integrity, making the polymer highly resistant to degradation under extreme conditions. The ether linkages add flexibility to the molecular chain, improving processability, while the ketone groups increase the polymer’s resistance to heat and oxidation. The semi-crystalline nature of PAEK arises from the ability of the polymer chains to pack efficiently in an ordered manner, leading to excellent wear resistance and high mechanical performance. Different types of PAEK, such as PEEK, PEK, and PEKK, vary in the arrangement and proportion of these functional groups, influencing their thermal and mechanical properties. This unique molecular structure makes PAEK an ideal choice for high-performance applications in aerospace, medical, automotive, and industrial sectors.
PropertiesPolyArylEtherKetone (PAEK) is a high-performance, semi-crystalline thermoplastic known for its exceptional mechanical, thermal, and chemical properties. It exhibits excellent strength, stiffness, and wear resistance, making it ideal for demanding applications in aerospace, automotive, medical, and oil and gas industries. PAEK has outstanding thermal stability, withstanding continuous use temperatures of up to 250°C, while also demonstrating remarkable resistance to chemicals, including acids, bases, and organic solvents. It possesses low moisture absorption, ensuring dimensional stability even in humid environments. Furthermore, PAEK offers excellent fatigue resistance, making it suitable for long-term load-bearing applications. Its inherent flame retardancy and low smoke emission enhance safety in high-temperature environments. Additionally, PAEK maintains excellent electrical insulation properties, making it valuable for electronic and electrical applications. These unique characteristics make PAEK an advanced material choice for extreme engineering conditions.
Applications of PolyArylEtherKetone (PAEK):
- Aerospace & Automotive: Used in structural components, bearings, and bushings due to its lightweight, high strength, and temperature resistance.
- Medical Devices: Ideal for implants, surgical instruments, and dental components due to biocompatibility and sterilization resistance.
- Oil & Gas Industry: Used in seals, valves, and insulators for its excellent chemical and high-temperature resistance.
- Electronics & Electrical: Utilized in connectors, insulators, and semiconductor manufacturing for its electrical insulation and heat resistance.
- Industrial & Manufacturing: Used in gears, pumps, and wear-resistant parts due to its high mechanical strength and low friction.
Advantages of PolyArylEtherKetone (PAEK):
- High Thermal Stability: Can withstand continuous temperatures up to 250°C.
- Excellent Mechanical Properties: High strength, stiffness, and impact resistance.
- Chemical Resistance: Withstands harsh chemicals, acids, and solvents.
- Low Moisture Absorption: Ensures dimensional stability in humid environments.
- Good Wear & Fatigue Resistance: Ideal for long-term, high-load applications.
- Flame Retardant & Low Smoke Emission: Enhances safety in high-temperature applications.
- Biocompatibility: Suitable for medical implants and surgical devices.
Disadvantages of PolyArylEtherKetone (PAEK):
- High Cost: More expensive than conventional plastics and some high-performance polymers.
- Difficult Processing: Requires high temperatures and specialized equipment for manufacturing.
- Limited Availability: Not as widely produced as other engineering plastics, leading to supply constraints.
- Brittleness at Low Temperatures: Can become less impact-resistant in extreme cold conditions.
Suspension
StructurePolyvinyl Chloride (PVC) suspension grade is a thermoplastic polymer produced through the suspension polymerization process. In this method, vinyl chloride monomer (VCM) is dispersed in water with the help of suspending agents and polymerized using free radical initiators. The resulting PVC resin consists of fine, porous, and free-flowing particles with a relatively high molecular weight, making it suitable for a wide range of applications. The polymer structure is primarily composed of repeating vinyl chloride units (–CH₂–CHCl–), forming a linear polymer chain with varying degrees of polymerization. PVC suspension grade is widely used in the manufacturing of pipes, fittings, films, sheets, and rigid as well as flexible products due to its excellent mechanical strength, durability, and chemical resistance. The properties of the resin, such as particle size, porosity, and bulk density, can be adjusted by controlling the polymerization conditions, making it versatile for different industrial applications.
PropertiesPVC suspension grade exhibits a combination of excellent physical, mechanical, and chemical properties, making it highly versatile for industrial applications. It appears as a white, free-flowing powder with a bulk density ranging from 0.45 to 0.65 g/cm³ and a particle size typically between 50-250 microns. Its high porosity allows for better plasticizer absorption, making it suitable for both rigid and flexible products. Mechanically, it offers good tensile strength, typically between 40-60 MPa, and moderate to high impact resistance, which can be enhanced with additives. Chemically, PVC suspension grade is highly resistant to acids, bases, and many chemicals, ensuring durability in harsh environments. It also has low water absorption, which provides excellent dimensional stability. However, it is susceptible to UV degradation, requiring stabilizers for outdoor applications. These properties make PVC suspension grade ideal for manufacturing pipes, profiles, films, and various other rigid and flexible products.
Applications
- Construction Industry: Pipes, fittings, window profiles, doors, roofing sheets
- Packaging Industry: Films, sheets, bottles
- Automotive Industry: Interior trims, dashboards, wire insulation
- Medical Sector: Tubing, blood bags, IV containers
- Electrical Applications: Cable insulation, coatings
Advantages
- High durability and strength – Ideal for long-term use
- Excellent chemical resistance – Withstands acids, bases, and oils
- Cost-effective – Affordable compared to other polymers
- Low water absorption – Ensures dimensional stability
- Easily processable – Can be molded, extruded, and shaped easily
- Customizable – Properties can be modified with additives
Disadvantages
- UV degradation – Becomes brittle under prolonged sunlight exposure
- Toxic gas release – Emits harmful gases (HCl) when burned
- Health concerns – Some plasticizers used in flexible PVC may have risks
- Not biodegradable – Raises environmental concerns regarding disposal
Thermoplastic PolyAmide elastomer (TPA)
StructureThe structure of Thermoplastic Polyamide Elastomer (TPA) consists of a phase-separated morphology with alternating soft and hard segments. The soft segments are typically composed of polyether or polyester chains, which provide flexibility, elasticity, and low-temperature performance. The hard segments are derived from polyamide (nylon) components, contributing to mechanical strength, chemical resistance, and thermal stability. This block copolymer structure allows TPAs to exhibit both rubber-like elasticity and thermoplastic processability. The hard polyamide domains act as physical crosslinks, reinforcing the material and providing shape stability, while the soft segments allow for stretchability and energy absorption. This unique microstructure enables TPAs to maintain excellent mechanical properties while being reprocessable and recyclable like conventional thermoplastics.
PropertiesThermoplastic Polyamide Elastomer (TPA) exhibits a unique combination of flexibility, strength, and chemical resistance, making it a highly versatile material. It possesses high elasticity and excellent recovery, allowing it to behave like rubber while maintaining thermoplastic processability. TPAs offer superior mechanical strength, abrasion resistance, and durability, making them suitable for demanding applications. They also demonstrate outstanding chemical and oil resistance, particularly against fuels, solvents, and industrial chemicals, which enhances their performance in harsh environments. Additionally, TPAs have good thermal stability, allowing them to withstand a wide range of temperatures without significant degradation. However, due to their hygroscopic nature, they tend to absorb moisture from the environment, requiring proper drying before processing. Despite this, their lightweight nature, recyclability, and ease of processing through standard thermoplastic methods such as injection molding and extrusion make TPAs an attractive choice for various industries, including automotive, electronics, and medical applications.
Applications of TPA
- Automotive: Fuel lines, air ducts, seals, gaskets, and hoses.
- Electronics: Wire insulation, connectors, and protective casings.
- Medical Devices: Tubing, catheters, flexible components, and grips.
- Industrial Machinery: Conveyor belts, seals, vibration dampeners, and flexible couplings.
- Sports & Consumer Goods: Shoe soles, flexible grips, protective gear, and wear-resistant textiles.
Advantages of TPAHigh chemical and oil resistance – Withstands fuels, solvents, and industrial chemicals. Excellent mechanical strength – Offers toughness, durability, and abrasion resistance. Good flexibility and elasticity – Provides rubber-like properties with thermoplastic processing benefits. Wide temperature range stability – Performs well in both high and low temperatures. Lightweight and recyclable – More sustainable compared to traditional rubber. Easy processing – Can be injection molded, extruded, or blow molded.
Disadvantages of TPAHigher cost – More expensive than standard thermoplastic elastomers (TPEs). Hygroscopic nature – Absorbs moisture, requiring drying before processing. Lower flexibility than fully vulcanized rubber – May not match the elasticity of certain elastomers. Limited UV resistance – Some grades may require UV stabilizers for outdoor applications.
Thermoplastic PolyOlefins (TPO)
StructureThermoplastic polyolefins (TPOs) have a heterogeneous polymer structure, consisting of a semi-crystalline polypropylene (PP) matrix blended with amorphous elastomeric domains, typically ethylene-propylene-diene monomer (EPDM) or ethylene-propylene rubber (EPR). The PP component provides rigidity, thermal stability, and strength, while the elastomeric phase contributes flexibility, impact resistance, and toughness. Unlike copolymers, TPOs maintain a phase-separated microstructure, where the rubber particles are dispersed within the PP matrix rather than chemically bonded. This structure allows TPOs to remain thermoplastic, meaning they can be melted and reprocessed without undergoing permanent chemical cross-linking. Additionally, the presence of optional fillers such as talc, glass fibers, or carbon black can modify properties like stiffness and durability. The balance between the crystalline regions of PP and the amorphous elastomer phase gives TPOs their unique combination of strength, flexibility, and recyclability, making them ideal for applications in automotive parts, roofing membranes, and flexible packaging materials.
PropertiesThermoplastic Polyolefins (TPOs) possess a unique combination of mechanical, thermal, chemical, and electrical properties that make them highly versatile in various applications. Mechanically, they offer high impact resistance, good flexibility, and moderate stiffness, thanks to the combination of a semi-crystalline polypropylene (PP) matrix and elastomeric components such as ethylene-propylene rubber (EPR) or EPDM. They also exhibit excellent tear and abrasion resistance, making them durable in demanding environments. Thermally, TPOs can withstand temperatures up to 120–140°C, with a relatively low melting point (~165°C for the PP phase), allowing for easy processing via injection molding, extrusion, and thermoforming. Chemically, they are highly resistant to oils, greases, solvents, acids, and bases, and with proper stabilization, they offer good UV and weather resistance, making them suitable for outdoor applications such as automotive exteriors and roofing membranes. Additionally, TPOs have low water absorption, ensuring dimensional stability in humid conditions. Electrically, they function as good insulators, making them useful in select wire and cable applications. Their thermoplastic nature allows for melting and reshaping, making them highly recyclable and environmentally friendly compared to traditional thermoset rubbers. Moreover, TPOs are lightweight, contributing to fuel efficiency in automotive applications and reducing material costs. These combined properties make TPOs ideal for automotive bumpers, flexible packaging, consumer goods, and construction materials.
Applications of Thermoplastic PolyOlefins
- Automotive Industry:
- Bumpers and fascias
- Interior trim panels and dashboard components
- Weather seals and underbody shields
- Lightweight structural parts for fuel efficiency
- Roofing & Construction:
- TPO roofing membranes (waterproof and UV-resistant)
- Flexible building materials and siding
- Window and door seals
- Consumer Goods:
- Sporting equipment (e.g., soft-touch grips, protective gear)
- Medical components (due to chemical resistance)
- Household items like storage bins and furniture components
- Packaging Industry:
- Rigid and flexible food containers
- Industrial packaging solutions
- Electrical & Electronics:
- Wire and cable insulation
- Protective casings for devices
Advantages of Thermoplastic PolyOlefinsHigh Impact Resistance – Absorbs shocks and mechanical stress effectively Flexible Yet Durable – Balances elasticity with structural integrity Excellent Weather & UV Resistance – Ideal for outdoor applications Good Chemical & Water Resistance – Resists oils, solvents, and moisture Lightweight – Reduces material costs and improves fuel efficiency in vehicles Easy to Process & Mold – Can be injection molded, extruded, or thermoformed Thermoplastic & Recyclable – Can be reprocessed, making it an eco-friendly choice Cost-Effective – Lower production costs compared to thermoset rubbers
Disadvantages of Thermoplastic PolyOlefinsLower Heat Resistance – Limited to around 120–140°C, making it unsuitable for high-heat applications Lower Stiffness Compared to Some Plastics – May require reinforcement (e.g., glass fibers) for structural strength Surface Finish Limitations – May require coatings or treatments for improved aesthetics Difficult to Bond with Adhesives – Requires specialized bonding techniques due to low surface energy Can Become Brittle in Extreme Cold – Some formulations may lose flexibility at very low temperatures
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