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Di Ethanol Amine

Diethanolamine (DEA) is an organic compound containing two hydroxyl (-OH) groups and one secondary amine (-NH-) group.
It belongs to the class of secondary amines and di-alcohols (dialkanolamines), exhibiting both amine and alcohol reactivity.
Due to this dual functionality, DEA acts as a weak base, emulsifier, pH stabilizer, and metal ion complexing agent in numerous industrial formulations.

Molecular Structure:
HO–CH₂–CH₂–NH–CH₂–CH₂–OH


Chemical and Physical Properties

Property Specification
Appearance Colorless to pale-yellow viscous liquid
Odor Mild ammonia-like odor
Molecular Weight 105.14 g/mol
Boiling Point ~269 °C (at atmospheric pressure)
Density (20–25 °C) 1.097 g/cm³
Solubility Completely miscible with water, ethanol, and glycerol; insoluble in hydrocarbons
pH (1% aqueous solution) 10.0–11.5
Chemical Nature Weak base, hygroscopic, non-volatile

Applications of Diethanolamine (DEA)

1. Detergent, Cosmetic, and Personal Care Industries

  • Active base for the formulation of shampoos, liquid soaps, creams, and lotions

  • pH regulator and stable emulsifier in surfactant systems

2. Oil and Gas Industry

  • Used for acid gas removal (COâ‚‚ and Hâ‚‚S) in gas sweetening units

  • Acts as a corrosion inhibitor in pipeline and refinery systems

3. Agriculture and Fertilizer

  • Serves as a chelating agent in liquid fertilizers

  • Functions as a pH stabilizer in pesticide and fungicide formulations

4. Paints, Inks, and Resins

  • Co-emulsifier in water-based coatings

  • Improves viscosity, stability, and durability of paints and inks

5. Cement and Construction

  • Used as a Grinding Aid in cement production

  • Enhances workability and compressive strength of concrete under varying temperatures


Advantages

  • Multi-functional and cost-effective across various industries

  • Excellent chemical stability in alkaline media

  • High solubility in aqueous systems

  • Compatible with surfactants, oils, and alcohols


Limitations

  • Irritant to skin and eyes upon direct contact

  • Potential formation of carcinogenic nitrosamines in the presence of nitrites

  • Sensitization risk in long-term exposure, especially in leave-on cosmetic products

  • Requires dose control in food and pharmaceutical-related applications


Safety and Regulatory Information (GHS / SDS)

  • H302: Harmful if swallowed

  • H315: Causes skin irritation

  • H319: Causes serious eye irritation

  • H351: Suspected of causing cancer (IARC Group 2B – limited evidence in humans)


Storage and Handling

  • Store in tightly sealed containers made of polyethylene or stainless steel

  • Keep in a cool, dry, and well-ventilated area (10–30 °C)

  • Protect from direct sunlight, heat sources, and oxidizing agents

  • Use chemical-resistant gloves, safety goggles, and adequate ventilation during handling


Summary

Diethanolamine (DEA) is a versatile alkanolamine used extensively in detergents, gas treatment, agricultural chemicals, and resin production.
Its dual functionality as both an amine and an alcohol makes it a valuable intermediate, though it requires strict handling and dosage control due to toxicity and sensitization potential.

Di Ethanol Amine